|
|
S-adenosyl-L-methionine + 4-dimethylallyl-L-tryptophan <=> 4-dimethylallyl-L-abrine + S-adenosyl-L-homocysteine + H+
|
2.1.1.261
4-dimethylallyltryptophan N-methyltransferase
|
–
|
|
BRENDA:
BR50272
KEGG:
R10166
MetaCyc:
RXN-11386
|
|
|
|
dimethylallyl_diphosphate + L-tryptophan <=> 4-dimethylallyl-L-tryptophan + diphosphate
|
2.5.1.34
4-dimethylallyltryptophan synthase
|
–
|
|
BRENDA:
BR47466
KEGG:
R01657;
R02943
MetaCyc:
TRYPTOPHAN-DIMETHYLALLYLTRANSFERASE-RXN
SABIO-RK:
1792
|
|
|
|
chanoclavine-I + NAD+ <=> chanoclavine-I_aldehyde + NADH + H+
|
1.1.1.332
chanoclavine-I dehydrogenase
|
–
|
|
BRENDA:
BR50141
KEGG:
R10128
MetaCyc:
RXN-13468
SABIO-RK:
14853
|
|
|
|
4-dimethylallyl-L-abrine + H2O + H+ + acceptor <=> chanoclavine-I + CO2 + reduced_acceptor
|
not assigned
|
–
|
|
MetaCyc:
RXN-11389
|
|